Saturday 26 January 2013

Classification & Elements, Compounds and Mixtures




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Activity 1: We listed all the soft toys we had. We were then asked to classify them into groups.


List
  • Teddy bear 
  • Dog 
  • Rabbit 
  • Giraffe
  • Duck
  • Sheep
  • Monkey 
  • Snake
  • Elephant 
  • Lion
  • Hyena 
  • Turtle
  • Panda
  • Hamster
  • Polar bear
  • Ponyo
  • Totoro
  • Carebears
  • Shrek 
  • Grizzly Bear
  • Koala
  • Angry Birds
  • Mickey Mouse
  • Doll
  • Kangaroo
  • Dolphin
  • Pooh
  • Eeyore
  • Wombat
  • Puppy
  • Stitch 
  • Penguin
  • Piglet
  • St. Bernard
  • Ninja

We classified these into 2 groups, “Animals that exist in real life” and “Fictional Characters”.

This is our classification chart:



Activity 2: We were given 12 different diagrams and were asked to classify them. We decided to classify them into 3 groups, “Elements”,  “Compounds” and “Mixtures”.

This is our classification chart:





Pre-reading of Elements, Compounds and Mixtures - My Notes

Determining Purity



  • A pure substance is made up of only one substances and is not mixed with any other substance. (e.g. white diamond)
  • Important to determine purity as impurities in medicine may produce undesirable effects
  • Important to ensure our food and drinks contain only chemicals that are safe for consumption
- How to determine purity?
  • A pure solid has an exact and constant (or fixed) melting point --> it will melt completely at one fixed temperature
  • Impurities lower the melting point (more impurities --> lower the melting point)
  • Impurities cause melting to take place over a range of temperatures
  • A pure liquid has an exact and constant (or fixed) boiling point.
  • Impurities increase the boiling point (more impurities --> higher the boiling point)
  • Impurities cause the liquid to boil over a range of temperatures
  • If the pressure acting on a liquid increases, the boiling point is also raised and vice versa. 

Chromatography


  • To test whether all the dyes in food colouring are safe for us to consume
  • Chromatography is technique of using a solvent to separate its mixture into its components. (paper chromatography)
  • Used to separate dyes in ink/pigments in plants/amino acids obtained from proteins to identify poisons or drugs, and to detect traces of banned substances in food
  • 2 ways paper chromatography is carried out
    --> Add the solvent to make the substance spread out on circular chromatography paper, to form rings showing the different dyes the ink is made up of.


--> Allow the solvent to ascend/travel up the chromatography paper

  • The chromatography paper with the separated components is called a chromatogram.
  • If there is only one spot on the chromatogram, it means the substance is pure.
  • The ratio between the distance travelled by the substance and the distance travelled by the solvent - Rf value (constant as long as chromatography is carried out with the same solvent and at the same temperature)
  • Rf value = distance travelled by the substance divided by distance travelled by solvent
  • Identical dyes produce spots at the same height and in the same colour on the paper when the same solvent is used. 
  • A locating agent is used to convert colourless chemicals into coloured chemicals that can be seen on the chromatogram. 
  • Uses --> separate the components in a sample, identify the number of components in a sample, identify the components present in a sample and determine whether a sample is pure.
Separation Techniques

How to separate:

(a) A solid from a liquid
(b) Solids
(c) A liquid from a solution
(d) Liquids

Decanting


  • To separate a dense, insoluble solid from a liquid
  • Process: Pouring the water away
Filtration
  • To separate small solid particles (sand, clay, dust particles and precipitates) from a liquid
  • Process:
    1. Fold the filter paper into quarters and open it up into a cone shape.
    2. Line the filter funnel with the filter paper.
    3. Pour the mixture into the filter funnel.
    4. Collect the filtrate that passes through the filter paper, in a conical flask.
    5. Wash the residue left in the filter paper with distilled water and leave it to dry on filter paper.
  • The solid that remains on the filter paper is called residue.
  • The liquid or solution that passes through the filter paper is called the filtrate.
Evaporation to dryness
  • To separate substances that dissolve in water by evaporating water from the solution.
  • NOT a good method of purification for substances that decompose when heated strongly. When the water is removed, any soluble impurities present will also be left behind.
Crystallisation
  • To obtain a pure solid sample from its solution
  • Process:
    1. Water is removed by heating the solution until a hot saturated solution is formed.
    2. When this resulting solution is allowed to cool to room temperature, the dissolved solid will be formed to pure crystals.
  • How do we test for a saturated solution(can be produced by evaporation)?
    - Dip a clean glass rod into the solution. If the small amount of solution that sticks onto the rod forms into crystals as the solution cools, the solution is saturated.
Dissolving and Filtration
  • To separate a mixture where one substance is soluble and the other is insoluble in a solvent.
Magnetism
  • To separate magnetic materials from non-magnetic materials
  • Magnets are used in recycling to recover magnetic materials from domestic waster.
Sublimation
  • To separate a substance that sublimes (e.g. ammonium chloride, iodine) from one with a high melting point (sand or sodium chloride).
Simple Distillation
  • To separate a pure solvent from a solution
  • Process: Boiling the liquid and condensing the vapour.
NOTE!
  • - The thermometer should be placed beside the side arm of the distillation flask. This ensures that the thermometer measures the boiling point of the substance that is being distilled.
  • Cold running water enters the condenser from the bottom and leaves form the top.
  • The condenser slopes downwards.
  • If the distillate it volatile, the receiver can be put in a large container filled with ice. This is to keep the temperature low and thus, maintain the distillate in its liquid state.
  • Used to:
    - Recover a solvent from a non-volatile solute
    - Separate mixtures of liquids with different boiling points (BOILING POINTS WHICH DIFFER BY LESS THAN 20 DEGREES CELSIUS IS DIFFICULT TO BE SEPARATED BY SIMPLE DISTILLATION) 
Separating Funnel
  • To separate immiscible liquids (liquids that do not dissolve in each other - e.g. oil and water)
Fractional Distillation
  • To separare a solution of miscible liquids (e.g. ethanol and water)
  • A fractionating column is attached to the round-bottomed flask and the condenser.
  • Many glass beads (plates/a spiral) in the fractionating column provide a larger surface area for vapour to condense on.
  • Process:
    - The liquid with the lowest boiling point will distil over to the condenser first.
    - The vapours of liquids with higher boiling points condense along the fractionating column and re-enter the round-bottomed flask. 
  • Industrial applications of fractional distillation:

  1. Fractional distillation is used in industries to obtain nitrogen, argon and oxygen from air.
  2. Fractional distillation can be used to separate mixtures of liquids such as crude oil.
  3. Ethanol is formed when glycose solution undergoes fermentation in the presence of yeast. We can separate ethanol from glucose solution by fractional distillation.














·    Matter can be classified into elements, compounds and mixtures.

·    An element is a pure substance that cannot be split up into two or more simpler substances by chemical processes or by electricity.


·    Chemical changes (chemical reactions) –

      -       Sugar -----> carbon + water (not easily reversed)
      -       Melting of wax
      -       Rusting

·    Physical changes

      -       water (liquid) à water (gas) [easily reversed]

·    Compounds:

      -       Formed by chemical reactions                    e.g. burning of magnesium in oxygen to form magnesium oxide

      -       The properties of compounds are different from the properties of its constituent

      -       Compounds have fixed compositions. (e.g.  water is always made of 11% oxygen and 89% hydrogen)

·      Breaking a compound:

      -       By decomposition (thermal decomposition
      -       By electrolysis

         ·            The boiling point/melting point of a substance can be used to determine the purity of the substance.

Naming elements

     ·      Standardized internationally by IUPAC
     ·      Some named after countries
     ·      Names of Elements
     ·      Names of elements in Latin

     ·      Our body is made up of 26 elements
      
·      Oxygen
·      Hydrogen
·      Carbon
·      Calcium
·      Nitrogen
·      Phosphorus
·      Other elements

         ·            Element Song: 
          http://www.privatehand.com/flash/elements.html

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